By Alan Buis; United States. National Aeronautics and Space Administration.; Jet Propulsion Laboratory (U.S.)
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Extra resources for Orbiting carbon observatory : science writers' guide
Nitrogen pressure (fugacity) build-up occurs at the contact surface. Even when the phase diagrams as a function of the Nrpartial pressure are known, it is still difficult to make a prediction because of experimental problems in determining the pressure at the interfaces. The present paper provides a framework for evaluation of the reactions at Si3Nimetal interfaces. References I. 2. 3. 4. 5. 6. 7. S. 9. J. (1990) Multiphase diffusion in binary and ternary solid state systems, Progress in Solid State Chemistry 20, 47-99.
CHATAIN, V. GHEITA· AND 1. FOULETIER·· CRMC2-CNRS Campus de Lummy, Case 913, 13288 Marseille; France ·LTPCM -INPG, "LEPM/-INPG Domaine Universitaire, BP 75, Saint-Martin-d'Heres, France ABSTRACT Wetting results from a balance of the free energies of two surfaces and an interface meeting at a triple line. Metal-oxide systems are in bulk chemical equilibrium if the activities of each of the components are identical in the metal, oxide and vapor phases which con,stitute the system. e. the chemical state of the surfaces and the interface, and the physical state of the oxide surface.
As an example, let us consider the surface of an A-B solution in which B is dilute and surface active. This A-rich solution is the single condensed phase in the A-B binary system up to a chemical potential ofB Of~Blim. At ~Blim the A-rich phase coexists with a B-rich phase, and at higher ~B only the B-rich phase is present. Fig. 2 displays the schematic behavior of the A-rich phase surface free energy, and of the B adsorption, as 47 the chemical potential of B increases up to the solubility limit.
Orbiting carbon observatory : science writers' guide by Alan Buis; United States. National Aeronautics and Space Administration.; Jet Propulsion Laboratory (U.S.)