Download e-book for iPad: New Solid Acids and Bases by K. Tanabe

By K. Tanabe

ISBN-10: 0080887554

ISBN-13: 9780080887555

ISBN-10: 0444988009

ISBN-13: 9780444988003

This quantity summarises and studies the large development revamped the earlier twenty years in sturdy acids and bases, with emphasis on primary facets and chemical rules. lately many new forms of good acids and bases were came across and synthesized. the outside homes (in specific, acidic and uncomplicated homes) and the constructions of the hot solids were clarified through newly built size tools utilizing sleek tools and methods. The characterised strong acids and bases were utilized as catalysts for diverse reactions, many stable correlations being acquired among the acid-base homes and the catalytic actions or selectivities. lately, acid-base bifunctional catalysis on good surfaces is turning into a a growing number of vital and interesting box of research. it's been well-known that the acidic and uncomplicated houses of catalysts and catalyst helps play an incredible position in oxidation, relief, hydrogenation, hydrocracking, and so forth.

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Extra resources for New Solid Acids and Bases

Example text

Collucia, E. Garrone, L. Cerruti, A. Zecchina,J. C h m . , Faraday Trans. 1, 75, 96 (1979). 9. Y. Fukuda, K. Tanabe, Bull. C h n . , 46 1616 (1973). 10. V. L. Whateley, Trans. , 63, 2769 (1967). 1 1 . G. Zhang, H. Hattori, K. Tanabe, Appl. , 36, 189 (1988). 12. G. Wang, H. Hattori,J. C h n . , 1 , 80, 1039 (1984). 13. T. Ito, M. Kuramoto, M. Yoshida, T. Tokuda, J. Phys. , 87, 4411 (1983). 14. T. Ito, T. Murakami, T . Tokuda,J. C h . , Trans. Faraday 1, 79, 913 (1983). 15. T. Ito, T . Sekino, N.

T i 0 2 a. ” The highest acid strength of Ti02 thus prepared was H o i - 3 , but the acid amount was very small. 11 mmol/g at H o l + 4 . 0 . No basic property was observed on Ti02 calcined at any temperature. ') Differential thermal analysis, showed an endothermic peak at 343 K. 5 which was much larger than the value in Table 3 . 2' The effect of aging of precipitates is fairly large. The structure of the latter T i 0 2 was only anatase even when calcined at 773 K and the crystallization began at 623 K.

Schwieger, Chm. Phys. , 128, 62 (1986). D. Freude, Advan. , 23, 21 (1985). E. C. E. Maciel, J . Am. C h m . , 110, 2023 (1988). 37. E. F. Haw, I-S. L. A. R. McKay, L. Petrakis,J. Am. Chem. , 105, 5529 (1983). 38. H . Kita, N. Henmi, K. Shimazu, H. Hattori, K. Tanabe,J. C h m . , Faraday Trans. 1, 77, 2451 (1981). 39. M . R . Basila, T . R . Kantner, J . Phys. C h . ,71, 467 (1967). 40. P. Parry,J. , 2, 371 (1963). 41. T . Sumiyoshi, K. Tanabe, H. Hattori, Bull. Jpn. Pcfrol. , 17, 65 (1975). 42.

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New Solid Acids and Bases by K. Tanabe


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