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Extra resources for Chemical Reaction and Reactor Engineering (Chemical Industries)
T hus , behavior is seen for me as u rem en t s t aken at conversion close to 1 , while the " ne gative order kinetics" ( i . e . , the in fluence of CO inhibition ) is observed n e i lar ge inlet CO concentration . I n tr ap ar ticle mass tran s fer resi st anc e is measured on pellets of differ ent si ze . Jackson ( 1 9 7 7 , C h ap . 10) reviews t he subj ect of di ffu si vit y me asurement s by steady - st ate methods as w e l l as by t r an sie nt me t ho d s . It may be safer to meas ure t he transport parameters un der re ac tin g condi tions .
C urve Bi : 0 > 0 ( 1 ) ; Bi u calc ulatea from Eqs . ( 91) and ( 9 2) . == 8 P 26 Villadsen and Mic helsen T he lower branch of the n versus ¢ curve is well approxi mated by one- point collocation ( curve marked " c " on Fig. 1 ) . For exam ple , at point A , w here ¢ 2 1 . 2 , one obtains ( ¢ * ) 2 :;;: 1 . 3 5 , and insertin g the modified 0 . 1 5 5 5 ] in Eq . ( 8 2) , one obtain s y 1 = 0 . 8 46 8 value of 6 [ S * :;;: 0 . 0 5 28 /9 an d n "' R ( y 1 ) = 1 . 7 0 2 , which may be compared w ith t h e exact result , 1 .
36) and ( 37) ] ; there is one nonlinear algebraic equation ( t he boundary con dition ) and N linear differential equations which can be trans formed into the diagonal form ( 18) and used in this form thro u ghout the calculation T he solution of E q s . ( 1 1 6 ) and ( 1 1 7) for a rate exp ression whic h is linear in y an d 9 ( or has been lineari zed from a given reference state) deserves p articular attention . C rank ( 1 95 7 ) has discussed the multitude o f practical proble m s in re action en gineerin g which are generated from t he same b asic equation , the linear " diffusion equation .
Chemical Reaction and Reactor Engineering (Chemical Industries) by Carberry