Atomic and Molecular Manipulation, Volume 2 by Andrew J. Mayne, Gérald Dujardin PDF

By Andrew J. Mayne, Gérald Dujardin

ISBN-10: 0080963552

ISBN-13: 9780080963556

Work with person atoms and molecules goals to illustrate that miniaturized digital, optical, magnetic, and mechanical units can function eventually even on the point of a unmarried atom or molecule. As such, atomic and molecular manipulation has performed an emblematic function within the improvement of the sphere of nanoscience. New tools in keeping with using the scanning tunnelling microscope (STM) were built to signify and manage the entire levels of freedom of person atoms and molecules with an unheard of precision. meanwhile, new techniques have emerged to layout molecules and substrates having particular optical, mechanical and digital capabilities, hence beginning the best way to the fabrication of genuine nano-machines. Manipulation of person atoms and molecules has additionally unfolded thoroughly new components of study and information, elevating basic questions of "Optics on the atomic scale", "Mechanics on the atomic scale", Electronics on the atomic scale", "Quantum physics on the atomic scale", and "Chemistry on the atomic scale". This publication goals to demonstrate the most features of this ongoing clinical experience and to count on the most important demanding situations for the longer term in "Atomic and molecular manipulation" from primary wisdom to the fabrication of atomic-scale devices.

  • Provides a large review of the sphere to assist these new and getting into this learn area
  • Presents a overview of the ancient improvement and evolution of the field
  • Offers a transparent customized view of present scanning probe microscopy learn from global experts

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Extra resources for Atomic and Molecular Manipulation, Volume 2

Sample text

97 REFERENCES 1. Eigler DM, Schweizer EK. Positioning single atoms with a scanning tunnelling microscope. Nature 1990;344(6266):524–6. 2. Ho W. Single-molecule chemistry. J Chem Phys 2002;117(24):11033–61. 3. Mayne AJ, Dujardin G, Comtet G, Riedel D. Electronic control of single-molecule dynamics. Chem Rev 2006;106(10):4355–78. 4. Cavar E, Blueml M-C, Pivetta M, Patthey F, Chergui M, Schneider W-D. Fluorescence and phosphorescence from individual C60 molecules excited by local electron tunneling.

4 V, Dz increases linearly with voltage, whereas for higher voltages, saturation is observed. 4 V is consistent with an exponential increase of the yield. The saturation rules out that the electric field in the tunnelling junction is responsible for the switching. 5 V. rent I needs to be extrapolated from I0 ¼ 10 pA at Dz ¼ 0 A Using an exponential extrapolation of I with Dz yields a decrease of about 10 orders of magnitude, which was quantified using an I (z) measurement at higher currents. There should also be a dramatic increase of the tunnelling current with increasing voltage because of tunnelling through the NIR state.

Following the discussion 36 Frontiers of Nanoscience of the dissociation of water molecules, we will present in detail three examples of how to controllably change the orbital structure by molecular manipulation. The first two of these examples discuss bond formation between a metal atom and a molecule to form metal molecule complexes. The third example discusses the realization of a unique planar molecular switch based on tunnelling-induced hydrogen tautomerization. 1. Manipulation of a Small Molecule: Water Dissociation on MgO Films One very important aspect of molecular manipulation on insulating films is related to the catalytic reactivity of oxides.

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Atomic and Molecular Manipulation, Volume 2 by Andrew J. Mayne, Gérald Dujardin

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